On the mechanism of the chemical and enzymic oxygenations of alpha-oxyprotohemin IX to Fe.biliverdin IX alpha.

alpha-Oxyprotohemin IX, an early intermediate in heme catabolism, was synthesized and its autoxidation to biliverdin IX alpha was studied. In anaerobic aqueous pyridine, alpha-oxyprotohemin (hexacoordinated) underwent autoreduction to yield an Fe(II) alpha-oxyprotoporphyrin pi-neutral radical bis(py...

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Bibliografiske detaljer

Udgivet i:	Proc Natl Acad Sci U S A
Principais autores:	Sano, S, Sano, T, Morishima, I, Shiro, Y, Maeda, Y
Format:	Artigo
Sprog:	Inglês
Udgivet:	National Academy of Sciences 1986
Fag:	Research Article
Online adgang:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC322897/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/3456152/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.83.3.531
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