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Nickel-catalyzed Asymmetric α-Arylation and Heteroarylation of Ketones with Chloroarenes: Effect of Halide on Selectivity, Oxidation State and Room Temperature Reactions
We report the α-arylation of ketone enolates with a range of aryl chlorides with enantioselectivities from 90% to 99% catalyzed by the combination of Ni(COD)(2) and (R)-BINAP, and the coupling of ketone enolates with a range of heteroaryl chlorides with enantioselectivities up to 99% catalyzed by Ni...
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| Huvudupphovsmän: | , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2011
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3214653/ https://ncbi.nlm.nih.gov/pubmed/21916501 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2082087 |
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