Llwytho...
Nickel-catalyzed Asymmetric α-Arylation and Heteroarylation of Ketones with Chloroarenes: Effect of Halide on Selectivity, Oxidation State and Room Temperature Reactions
We report the α-arylation of ketone enolates with a range of aryl chlorides with enantioselectivities from 90% to 99% catalyzed by the combination of Ni(COD)(2) and (R)-BINAP, and the coupling of ketone enolates with a range of heteroaryl chlorides with enantioselectivities up to 99% catalyzed by Ni...
Wedi'i Gadw mewn:
| Prif Awduron: | , |
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| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
2011
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3214653/ https://ncbi.nlm.nih.gov/pubmed/21916501 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2082087 |
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