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Metal-Sulfur Valence Orbital Interaction Energies in Metal–Dithiolene Complexes: Determination of Charge and Overlap Interaction Energies by Comparison of Core and Valence Ionization Energy Shifts

The electronic interactions between metals and dithiolenes are important in the biological processes of many metalloenzymes as well as in diverse chemical and material applications. Of special note is the ability of the dithiolene ligand to support metal centers in multiple coordination environments...

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Main Authors: Wiebelhaus, Nicholas J., Cranswick, Matthew A., Klein, Eric L., Lockett, L. Tori, Lichtenberger, Dennis L., Enemark, John H.
Format: Artigo
Jezik:Inglês
Izdano: 2011
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3205315/
https://ncbi.nlm.nih.gov/pubmed/21988484
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic201566n
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