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Combination of gold catalysis and Selectfluor for the synthesis of fluorinated nitrogen heterocycles
We herein report the synthesis of 3-fluoro-2-methylene-pyrrolidine (3a) and -piperidine (3b) from 1,5- and 1,6-aminoalkynes, respectively, using a combination of a gold-catalyzed hydroamination reaction followed by electrophilic trapping of an intermediate cyclic enamine by Selectfluor. Careful atte...
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| Autors principals: | , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Beilstein-Institut
2011
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3201052/ https://ncbi.nlm.nih.gov/pubmed/22043249 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.162 |
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