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Oxidation of phenylhydroxylamine in aqueous solution: a model for study of the carcinogenic effect of primary aromatic amines.

Phenylhydroxylamine is degraded in aqueous phosphate buffers at physiological pH values (6.8-7.4) to give nitrosobenzene, nitrobenzene, and azoxybenzene. The reaction is O2 dependent and subject to general acid and general base catalysis. At pH less than or equal to 5.8 in cacodylate buffer, it is c...

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Detalles Bibliográficos
Autores principales: Becker, A R, Sternson, L A
Formato: Artigo
Lenguaje:Inglês
Publicado: 1981
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC319270/
https://ncbi.nlm.nih.gov/pubmed/6941266
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