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Spectroscopic and Computational Studies of α-keto Acid Binding to Dke1: Understanding the role of the facial triad and the reactivity of β-diketones
The O(2) activating mononuclear non-heme iron enzymes generally have a common facial triad (2 histidine and one carboxylate (Asp or Glu) residue) ligating Fe(II) at the active site. Exceptions to this motif have recently been identified in non-heme enzymes, including a 3His triad in the diketone cle...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2011
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3191879/ https://ncbi.nlm.nih.gov/pubmed/21870808 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja203005j |
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