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Catalytic Asymmetric Thiofunctionalization of Unactivated Alkenes
The catalytic asymmetric sulfenylation of double bonds has been achieved using a BINAM-based phosphoramide catalyst and electrophilic sulfur source. Simple alkenes as well as styrenes afforded sulfenylated tetrahydrofurans and tetrahydropyrans by closure with pendant hydroxyl or carboxyl groups. Int...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2011
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3187834/ https://ncbi.nlm.nih.gov/pubmed/21859086 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2064395 |
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