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Lithium phosphonate umpolung catalysts: Do fluoro substituents increase the catalytic activity?
Fluorinated and nonfluorinated phosphonates are employed as precatalysts in lithium phosphonate catalyzed cross benzoin couplings. Surprisingly, a decreased catalytic activity for the fluorinated precatalysts compared to the nonfluorinated systems is observed. Furthermore, the ring size of six, seve...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3182427/ https://ncbi.nlm.nih.gov/pubmed/21977202 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.138 |
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