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Observation of an Acryloyl–Thiamin Diphosphate Adduct in the First Step of Clavulanic Acid Biosynthesis
[Image: see text] The first committed biosynthetic step toward clavulanic acid, the clinically-important β-lactamase inhibitor, is catalyzed by the thiamin diphosphate (ThDP)-dependent enzyme N(2)-(2-carboxyethyl)arginine synthase (CEAS). This protein carries out a unique reaction among ThDP-depende...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3180866/ https://ncbi.nlm.nih.gov/pubmed/18052280 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja076704r |
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