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Strong ferromagnetic metal-ligand exchange in a nickel bis(3,5-dipyridylverdazyl) complex

A new 1,5-dipyridyl verdazyl, synthesized from the corresponding dipyridyl hydrazone, coordinates nickel(II) to form a structurally characterized, pseudooctahedral complex analogous to Ni(terpy)(2)(2+). The unusually short Ni-verdazyl distance results in strong ferromagnetic exchange (J(Ni-rad)=+300...

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Detalhes bibliográficos
Main Authors: Brook, David J. R., Richardson, Cardius, Haller, Benjamin C., Hundley, Michael, Yee, Gordon
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3178463/
https://ncbi.nlm.nih.gov/pubmed/20697644
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c0cc02233k
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