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Metalloporphyrin Mixed-Valence π-Cation Radicals: [Fe(oxoOEC(./2))(Cl)](2)SbCl(6), Structure, Magnetic Properties, and Near-IR Spectra
The preparation and characterization of a mixed-valence π-cation radical derivative of an iron(III) oxochlorinato complex is reported. The new complex has been synthesized by the one-electron oxidation of a pair of [Fe(oxoOEC)(Cl)] molecules to form the dimeric cation [Fe(oxoOEC)(Cl)](+)(2). The cat...
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| Autors principals: | , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2011
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3171574/ https://ncbi.nlm.nih.gov/pubmed/21809820 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic201292t |
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