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Methylerythritol cyclodiphosphate (MEcPP) in deoxyxylulose phosphate pathway: synthesis from an epoxide and mechanismsw

In this communication, we reported another unique IspG-catalyzed transformation, the production of its substrate, MEcPP, from (2R,3R)-4-hydroxy-3-methyl-2,3-epoxybutanyl diphosphate (Epoxy-HMBPP) when reductants are excluded from the reaction mixture.

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Detalles Bibliográficos
Main Authors: Xiao, Youli, Nyland, Rodney L., Meyers, Caren L. Freel, Liu, Pinghua
Formato: Artigo
Idioma:Inglês
Publicado: 2010
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3170881/
https://ncbi.nlm.nih.gov/pubmed/20820543
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c0cc02594a
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