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A new scheme to calculate isotope effects

We present a new scheme to calculate isotope effects. Only selected frequencies at the target level of theory are calculated. The frequencies are selected by an analysis of the Hessian from a lower level of theory. We obtain accurate isotope effects without calculating the full Hessian at the target...

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Autori principali: Świderek, Katarzyna, Dybala-Defratyka, Agnieszka, Rohr, Daniel R.
Natura: Artigo
Lingua:Inglês
Pubblicazione: Springer-Verlag 2010
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3168760/
https://ncbi.nlm.nih.gov/pubmed/20957502
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00894-010-0868-4
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