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Functionalization of anthracene: A selective route to brominated 1,4-anthraquinones

Efficient and stereoselective syntheses are described for the preparation of 2,3,9,10-tetrabromo-1,4-dimethoxy-1,2,3,4-tetrahydroanthracenes 7, 8 and the corresponding 1,4-diol 17 by silver ion-assisted solvolysis of hexabromotetrahydroanthracene 6. Base-promoted aromatization of 7 and 8 afforded sy...

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Detalhes bibliográficos
Main Authors: Berkil Akar, Kiymet, Cakmak, Osman, Büyükgüngör, Orhan, Sahin, Ertan
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3167179/
https://ncbi.nlm.nih.gov/pubmed/21915205
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.118
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