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Trialkylborane-Assisted CO(2) Reduction by Late Transition Metal Hydrides
Trialkylborane additives promote reduction of CO(2) to formate by bis(diphosphine) Ni(II) and Rh(III) hydride complexes. The late transition metal hydrides, which can be formed from dihydrogen, transfer hydride to CO(2) to give a formate-borane adduct. The borane must be of appropriate Lewis acidity...
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| 主要な著者: | , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2011
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3167168/ https://ncbi.nlm.nih.gov/pubmed/21909178 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om200364w |
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