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Oxidative Coupling as a Biomimetic Approach to the Synthesis of Scytonemin
[Image: see text] The first total synthesis of the dimeric alkaloid pigment scytonemin is described. The key transformations in its synthesis from 3-indole acetic acid are a Heck carbocyclization and a Suzuki–Miyaura cross-coupling, orchestrated in a stereospecific tandem fashion, followed by a bios...
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| Hoofdauteurs: | , , , , , |
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| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
American Chemical Society
2011
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| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3164230/ https://ncbi.nlm.nih.gov/pubmed/21786790 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol201812n |
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