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A Stereoselective Inverting sec-Alkylsulfatase for the Deracemization of sec-Alcohols
[Image: see text] A metallo-β-lactamase-type alkylsulfatase was found to catalyze the enantioselective hydrolysis of sec-alkylsulfates with strict inversion of configuration. This catalytic event, which does not have an analog in chemocatalysis, yields homochiral (S)-configurated alcohols and nonrea...
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| Main Authors: | , , , , , , , , |
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| Formáid: | Artigo |
| Teanga: | Inglês |
| Foilsithe: |
American Chemical Society
2011
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| Rochtain Ar Líne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3155277/ https://ncbi.nlm.nih.gov/pubmed/21770430 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol201635y |
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