Reactions of the Tridentate and Tetradentate Amine Ligands di-(2-picolyl)(N-ethyl)amine and 2,5-Bis-(2-pyridylmethyl)-2,5 diazohexane with Technetium Nitrosyl Complexes

The reaction of the Tc(II) nitrosyl complex (Bu(4)N)[Tc(NO)Cl(4)] with Di-(2-picolyl)(NEt)amine in methanol yields the neutral complex [Tc(NO)Cl(py-N(Et)-py)]. The reaction of the Tc(I) nitrosyl complex [Tc(NO)Cl(2)(HOMe)(PPh(3))(2)] with this tridentate ligand yields cationic [Tc(NO)Cl(py-N(Et)-py)...

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Bibliografske podrobnosti
Main Authors: Nicholson, T., Mahmood, A., Limpa-Amara, N., Salvarese, N., Takase, M. K, Müller, P., Jones, A. G.
Format: Artigo
Jezik:Inglês
Izdano: 2011
Teme:
Article
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3152200/
https://ncbi.nlm.nih.gov/pubmed/21836726
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ica.2011.04.002
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