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Application of a New Chiral Phosphepine to the Catalytic Asymmetric Synthesis of Highly Functionalized Cyclopentenes that Bear an Array of Heteroatom-Substituted Quaternary Stereocenters

Through the design and synthesis of a new chiral phosphepine, the first catalytic asymmetric method for the [3+2] cycloaddition of allenes with olefins has been developed that generates cyclopentenes that bear nitrogen-, phosphorus-, oxygen-, and sulfur-substituted quaternary stereocenters. A wide a...

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Библиографические подробности
Главные авторы: Fujiwara, Yuji, Fu, Gregory C.
Формат: Artigo
Язык:Inglês
Опубликовано: 2011
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC3150361/
https://ncbi.nlm.nih.gov/pubmed/21766794
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2049012
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