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Application of a New Chiral Phosphepine to the Catalytic Asymmetric Synthesis of Highly Functionalized Cyclopentenes that Bear an Array of Heteroatom-Substituted Quaternary Stereocenters
Through the design and synthesis of a new chiral phosphepine, the first catalytic asymmetric method for the [3+2] cycloaddition of allenes with olefins has been developed that generates cyclopentenes that bear nitrogen-, phosphorus-, oxygen-, and sulfur-substituted quaternary stereocenters. A wide a...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3150361/ https://ncbi.nlm.nih.gov/pubmed/21766794 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2049012 |
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