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Rearrangement/Fragmentation Reactions of Oligosilanes with Aluminum Chloride

[Image: see text] Reinvestigation of the Lewis acid catalyzed rearrangement of some open-chain permethyloligosilanes with the Al(Fe)Cl(3) catalyst system exhibited several cases of additional reactivity: namely, a fragmentation/cyclization reaction. Introduction of (trimethylsilyl)methyl substituent...

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Detalhes bibliográficos
Main Authors: Wagner, Harald, Baumgartner, Judith, Marschner, Christoph, Poelt, Peter
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2011
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3148123/
https://ncbi.nlm.nih.gov/pubmed/21818171
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om1011165
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