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A Dinuclear Palladium Catalyst for α-Hydroxylation of Carbonyls with O(2)
A chemo- and regioselective α-hydroxylation reaction of carbonyl compounds with molecular oxygen as oxidant is reported. The hydroxylation reaction is catalyzed by a dinuclear Pd(II) complex, which functions as an oxygen transfer catalyst, reminiscent of an oxygenase. The development of this oxidati...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2011
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3139748/ https://ncbi.nlm.nih.gov/pubmed/21247109 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja108396k |
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