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Stress Relaxation by Addition-Fragmentation Chain Transfer in Highly Crosslinked Thiol-Yne Networks

Radical mediated addition-fragmentation chain transfer of mid-chain allyl sulfide functional groups was utilized to reduce polymerization-induced shrinkage stress in thiol-yne step-growth photopolymerization reactions. In previous studies, the addition-fragmentation of allyl sulfide during the polym...

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Autors principals: Park, Hee Young, Kloxin, Christopher J., Scott, Timothy F., Bowman, Christopher N.
Format: Artigo
Idioma:Inglês
Publicat: 2010
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3134880/
https://ncbi.nlm.nih.gov/pubmed/21765551
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ma1020209
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