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Synthesis of 4- and 4,5-Functionalized Imidazol-2-Ylidenes from a Single 4,5-Unsubstituted Imidazol-2-Ylidene
Using the nucleophilicity of NHCs and aNHCs, as well as the leaving group ability of the former, the carbon-carbon double bond of imidazol-2-ylidenes can be readily mono- and di-functionalized. These results provide also a new light on the formation of abnormal carbene adducts from classical unsatur...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2010
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3134311/ https://ncbi.nlm.nih.gov/pubmed/20443633 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja102639a |
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