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Reduction of the virtual space for coupled-cluster excitation energies of large molecules and embedded systems

We investigate how the reduction of the virtual space affects coupled-cluster excitation energies at the approximate singles and doubles coupled-cluster level (CC2). In this reduced-virtual-space (RVS) approach, all virtual orbitals above a certain energy threshold are omitted in the correlation cal...

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Bibliografski detalji
Glavni autori: Send, Robert, Kaila, Ville R. I., Sundholm, Dage
Format: Artigo
Jezik:Inglês
Izdano: American Institute of Physics 2011
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3133567/
https://ncbi.nlm.nih.gov/pubmed/21663351
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.3596729
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