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Controlling the Facial Selectivity of Asymmetric [4+2] Cyclo-additions: A Concise Synthesis of the cis-Decalin Core Structure of Superstolides A and B
[Image: see text] Regio, stereo and facial selective [4+2] cycloadditions between highly activated vinyl sulfones and 1,3-dienes derived from (R)-4-t-butyldimethyl-silyloxy-2-cyclohexen-1-one provide a powerful approach for the asymmetric synthesis of compounds containing the bicyclo[2.2.2]octanone...
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| Hauptverfasser: | , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2011
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3132299/ https://ncbi.nlm.nih.gov/pubmed/21671636 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol201095b |
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