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Crystalline 1H-1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs)
Until recently, the availability of neutral carbon-based κ(1)C ligands was limited to carbon monoxide, isocyanides, and carbenes. Compared to phosphorus-based ligands, carbenes tend to bind more strongly to metal centers, avoiding the necessity for the use of excess ligand in catalytic reactions. Th...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3131155/ https://ncbi.nlm.nih.gov/pubmed/20509134 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201001864 |
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