טוען...
Ligand Steric Contours to Understand the Effects of N-Heterocyclic Carbene Ligands on the Reversal of Regioselectivity in Ni-Catalyzed Reductive Couplings of Alkynes and Aldehydes
The regioselectivities of N-heterocyclic carbene (NHC) ligands in Ni-catalyzed alkyne–aldehyde reductive coupling reactions with silane reducing agents are investigated using density functional theory. Reversal of regioselectivities can be achieved by varying the steric bulkiness of the ligand. The...
שמור ב:
| Main Authors: | , , |
|---|---|
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2011
|
| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3128454/ https://ncbi.nlm.nih.gov/pubmed/21506540 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja202007s |
| תגים: |
הוספת תג
אין תגיות, היה/י הראשונ/ה לתייג את הרשומה!
|