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catena-Poly[[[tetra­kis­(cyanido-κC)tungstate(IV)]-di-μ-cyanido-κ(4) C:N-bis­[diaqua­(2,2′-bipyridyl-κ(2) N,N′)manganese(II)]-di-μ-cyanido-κ(4) N:C] hexa­hydrate]

The polymeric title compound, {[Mn(II) (2)W(IV)(CN)(8)(C(10)H(8)N(2))(2)(H(2)O)(4)]·6H(2)O}(n), has a one-dimensional cyanide-bridged Mn(II)–W(IV) bimetallic assembly. The coordination geometry of the W(IV) atom is eight-coordinate square-anti­prismatic and that of each of the Mn(II) atoms is six-co...

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Detalhes bibliográficos
Main Authors: Ozaki, Noriaki, Yamada, Ryo, Nakabayashi, Koji, Ohkoshi, Shin-ichi
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3120535/
https://ncbi.nlm.nih.gov/pubmed/21754606
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536811012451
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