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Formation of Iron Complexes from Trifluoroacetic Acid Based Liquid Chromatography Mobile Phases as Interference Ions in LC-ESI-MS Analysis

Two unexpected singly charged ions at m/z 1103 and 944 have been observed in mass spectra obtained from electrospray ionization-mass spectrometric analysis of liquid chromatography effluents with mobile phases containing trifluoroacetic acid that severely interfered with sample analysis. Accurate ma...

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Autori principali: Shukla, Anil, Zhang, Rui, Orton, Daniel, Zhao, Rui, Clauss, Therese, Moore, Ronald, Smith, Richard
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2011
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3120053/
https://ncbi.nlm.nih.gov/pubmed/21504012
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/rcm.5017
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