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Convergent and Stereodivergent Synthesis of Complex 1-Aza-7-Oxabicyclo[2.2.1]heptanes
A convergent and stereodivergent pathway to highly substituted 1-aza-7-oxabicyclo[2.2.1]heptanes is described. This process begins with a coupling reaction between an allylic alcohol, aldehyde, and LiHMDS for the production of stereodefined primary homoallylic amines. Subsequent N-oxidation and cond...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2011
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3116711/ https://ncbi.nlm.nih.gov/pubmed/21604673 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja202900h |
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