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Dinitrogen Complexes of Sulfur-ligated Iron

We report a unique class of dinitrogen complexes of iron featuring sulfur donors in the ancillary ligand. The ligands utilized are related to the recently studied tris(phosphino)silyl ligands, [SiP(R)(3)] ([SiP(R)(3)] = [(2-R(2)PC(6)H(4))(3)Si]; R = Ph, iPr), but have one or two phosphine arms repla...

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Autors principals: Takaoka, Ayumi, Mankad, Neal P., Peters, Jonas C.
Format: Artigo
Idioma:Inglês
Publicat: 2011
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3115625/
https://ncbi.nlm.nih.gov/pubmed/21574618
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2020907
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