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A Rapid, Asymmetric Synthesis of the Decahydrofluorene Core of the Hirsutellones

[Image: see text] A tandem ketene-trapping/Diels–Alder cyclization sequence was the pivotal transformation in an efficient, asymmetric synthesis of a decahydrofluorene tricyclic structure possessing eight stereogenic centers and key features of the hirsutellone class of antitubercular natural produc...

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Bibliographic Details
Main Authors: Tilley, S. David, Reber, Keith P., Sorensen, Erik J.
Format: Artigo
Language:Inglês
Published: 2009
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3115586/
https://ncbi.nlm.nih.gov/pubmed/19119873
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802768p
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