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Three-coordinate copper(I) amido and aminyl radical complexes
A three-coordinate Cu-NR(2) system (R = p-tolyl) supported by the anionic bis(phosphino)borate ligand [Ph(2)B(CH(2)P(t)Bu(2))(2)](−) has been isolated and structurally characterized in both its anionic Cu(I) and neutral (formally) Cu(II) oxidation states. A rapid rate constant k(S) ≥ 10(7) M(−1) s(−...
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| Main Authors: | , , , |
|---|---|
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2009
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3110787/ https://ncbi.nlm.nih.gov/pubmed/19253942 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja809834k |
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