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Superelectrophilic chemistry of amino-nitriles and related substrates
The superacid-promoted Houben-Hoesch reactions of amino-nitriles and related compounds have been studied. The nitriles form dicationic electrophiles and react with benzene in fair to good yields (12-95%). The intermediate iminium ions may also be reduced to the benzylic amines by NaBH(4) or H(2).
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3110710/ https://ncbi.nlm.nih.gov/pubmed/21666850 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2011.04.038 |
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