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Kinetic evaluation of the solvolysis of isobutyl chloro- and chlorothioformate esters

The specific rates of solvolysis of isobutyl chloroformate (1) are reported at 40.0 °C and those for isobutyl chlorothioformate (2) are reported at 25.0 °C, in a variety of pure and binary aqueous organic mixtures with wide ranging nucleophilicity and ionizing power. For 1, we also report the first-...

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Autori principali: D’Souza, Malcolm J, McAneny, Matthew J, Kevill, Dennis N, Kyong, Jin Burm, Choi, Song Hee
Natura: Artigo
Lingua:Inglês
Pubblicazione: Beilstein-Institut 2011
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3107482/
https://ncbi.nlm.nih.gov/pubmed/21647255
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.62
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