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Cell-free H-cluster Synthesis and [FeFe] Hydrogenase Activation: All Five CO and CN(−) Ligands Derive from Tyrosine
[FeFe] hydrogenases are promising catalysts for producing hydrogen as a sustainable fuel and chemical feedstock, and they also serve as paradigms for biomimetic hydrogen-evolving compounds. Hydrogen formation is catalyzed by the H-cluster, a unique iron-based cofactor requiring three carbon monoxide...
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| Autors principals: | , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Public Library of Science
2011
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3105041/ https://ncbi.nlm.nih.gov/pubmed/21673792 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1371/journal.pone.0020346 |
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