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Controlling the Photoreactivity of the Photoactive Yellow Protein Chromophore by Substituting at the p-Coumaric Acid Group

[Image: see text] We have performed ab initio CASSCF, CASPT2, and EOM-CCSD calculations on doubly deprotonated p-coumaric acid (pCA(2−)), the chromophore precursor of the photoactive yellow protein. The results of the calculations demonstrate that pCA(2−) can undergo only photoisomerization of the d...

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Detalhes bibliográficos
Main Authors: Boggio-Pasqua, Martial, Groenhof, Gerrit
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2011
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3102441/
https://ncbi.nlm.nih.gov/pubmed/21561119
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp108977x
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