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Mapping the Reaction Coordinates of Enzymatic Defluorination

The carbon-fluorine bond is the strongest covalent bond in organic chemistry, yet fluoroacetate dehalogenases can readily hydrolyze this bond under mild physiological conditions. Elucidating the molecular basis of this rare biocatalytic activity will provide the fundamental chemical insights of how...

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Détails bibliographiques
Auteurs principaux: Chan, Peter W. Y., Yakunin, Alexander F., Edwards, Elizabeth A., Pai, Emil F.
Format: Artigo
Langue:Inglês
Publié: 2011
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3101105/
https://ncbi.nlm.nih.gov/pubmed/21510690
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja200277d
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