Electron delocalization in the S(1) and T(1) metal-to-ligand charge transfer states of trans-substituted metal quadruply bonded complexes

The singlet S(1) and triplet T(1) photoexcited states of the compounds containing MM quadruple bonds trans-M(2)(T(i)PB)(2)(O(2)CC(6)H(4)-4-CN)(2), where T(i)PB = 2,4,6-triisopropylbenzoate and M = Mo (I) or M = W (I(′)), and trans-M(2)(O(2)CMe)(2)((N[(i) Pr ])(2)CC ≡ CC(6)H(5))(2), where M = Mo (II)...

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Detalhes bibliográficos
Main Authors: Alberding, Brian G., Chisholm, Malcolm H., Gallucci, Judith C., Ghosh, Yagnaseni, Gustafson, Terry L.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2011
Assuntos:
Physical Sciences
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3100943/
https://ncbi.nlm.nih.gov/pubmed/21525414
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1103082108
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