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Driving Catalyst Reoxidation in Wacker Cyclizations with Acetal-Based Metal-Hydride Abstractors
In traditional Wacker processes, Pd(II) becomes reduced to Pd(0) after C-O bond formation and β-H elimination and must be reoxidized to the electrophilic Pd(II) state via a stoichiometric oxidant like benzoquinone, CuCl(2), or O(2). We report herein a Pt-catalyzed Wacker-type process that regenerate...
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| Main Authors: | , , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2011
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3092479/ https://ncbi.nlm.nih.gov/pubmed/21572581 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om2001958 |
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