Suzuki–Miyaura Cross-Coupling of Aryl Carbamates and Sulfamates: Experimental and Computational Studies

The first Suzuki–Miyaura cross-coupling reactions of the synthetically versatile O-aryl carbamate and O-sulfamate groups is described. The transformations utilize the inexpensive, bench-stable catalyst NiCl(2)(PCy(3))(2) to furnish biaryls in good to excellent yields. A broad scope for this methodol...

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Bibliographic Details
Main Authors: Quasdorf, Kyle W., Antoft-Finch, Aurora, Liu, Peng, Silberstein, Amanda L., Komaromi, Anna, Blackburn, Tom, Ramgren, Stephen D., Houk, K. N., Snieckus, Victor, Garg, Neil K.
Format: Artigo
Language:Inglês
Published: 2011
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3091075/
https://ncbi.nlm.nih.gov/pubmed/21456551
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja200398c
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