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{2-[(η(5)-Cyclopentadienyl)diphenylmethyl]-1H-imidazolido-κN}bis(N,N-diethylamido)titanium(IV)
The chemically achiral title molecule, [Ti(C(4)H(10)N)(2)(C(21)H(16)N(2))], crystallizes in the chiral space group P2(1). All three N atoms coordinating to the Ti(IV) atom adopt planar environments [sums of valence angles = 359.5 (6), 360.0 (7) and 360.0 (6)°], which is indicative of pπ–dπ donation...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
International Union of Crystallography
2011
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3089115/ https://ncbi.nlm.nih.gov/pubmed/21754286 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536811012396 |
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