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Diasteroselective Preparation of Cyclopropanols Using Methylene Bis(iodozinc)
[Image: see text] A diastereoselective synthesis of trans-1,2-substituted cyclopropanols is outlined. Bimetallic CH(2)(ZnI)(2) was found to react with α-chloroaldehydes to give cyclopropanols in yields of 64–89% and dr’s ≥ 10:1. The high trans-selectivity resulted from equilibration of the cycloprop...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3084887/ https://ncbi.nlm.nih.gov/pubmed/21462964 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol200597h |
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