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Toward the total synthesis of maoecrystal V: an intramolecular Diels–Alder route to the maoecrystal V pentacyclic core with the appropriate relative stereochemistry
A diastereoselective route to the maoecrystal V core compound (6) has been achieved. Key transformations include an intramolecular Diels–Alder cyclization and an exo-glycal epoxide rearrangement sequence.
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3079889/ https://ncbi.nlm.nih.gov/pubmed/21516211 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2010.11.029 |
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