Europium(III) DOTA-derivatives having ketone donor pendant arms display dramatically slower water exchange

A series of new 1,4,7,10-tetraazacyclododecane-derivatives having a combination of amide and ketone donor groups as side-arms were prepared and their complexes with europium(III) studied in detail by high resolution NMR spectroscopy. The chemical shift of the Eu(3+)-bound water resonance, the chemic...

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Bibliographic Details
Main Authors: Green, Kayla N., Viswanathan, Subha, Rojas-Quijano, Federico A., Kovacs, Zoltan, Sherry, A. Dean
Format: Artigo
Language:Inglês
Published: 2011
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3077439/
https://ncbi.nlm.nih.gov/pubmed/21306137
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic101856d
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