Curvature-coupled hydration of Semicrystalline Polymer Amphiphiles yields flexible Worm Micelles but favors rigid Vesicles: polycaprolactone-based block copolymers

Crystallization processes are in general sensitive to detailed conditions, but our present understanding of underlying mechanisms is insufficient. A crystallizable chain within a diblock copolymer assembly is expected to couple curvature to crystallization and thereby impact rigidity as well as pref...

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Bibliographic Details
Main Authors: Rajagopal, Karthikan, Mahmud, Abdullah, Christian, David A., Pajerowski, J. David, Brown, Andre E.X., Loverde, Sharon M., Discher, Dennis E.
Format: Artigo
Language:Inglês
Published: 2010
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3075012/
https://ncbi.nlm.nih.gov/pubmed/21499509
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ma101316w
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