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Aliphatic C-H to C-C Conversion: Synthesis of (−)-Cameroonan-7α-ol

[Image: see text] In the course of a synthesis of the tricyclic sesquiterpene (−)-cameroonan-7α-ol from the acyclic (+)-citronellal, seven aliphatic C-H bonds were converted to C-C bonds, and three rings and four new stereogenic centers were established.

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Hlavní autoři: Taber, Douglass F., Nelson, Christopher G.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2011
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3074237/
https://ncbi.nlm.nih.gov/pubmed/21344897
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo200075v
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