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Functionalization of the corrole ring: the role of isocorrole intermediates

Bromination of 3-nitro-5,10,15-triarylcorrole selectively provides two regioisomers, depending on the reaction pathway. An isocorrole species is the key intermediate to drive the reaction towards the 2-Br-17-nitro regioisomer.

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Detalhes bibliográficos
Main Authors: Tortora, Luca, Nardis, Sara, Fronczek, Frank R., Smith, Kevin M., Paolesse, Roberto
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3070944/
https://ncbi.nlm.nih.gov/pubmed/21350743
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c0cc05837h
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