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Nitration of iron corrolates: further evidence for non-innocence of the corrole ligand

Mono- and di-substituted β-nitro derivatives have been obtained from the reaction of ttcorrFeCl with sodium nitrite in refluxing DMF. This result is unprecedented for iron corrolates and further evidences the non-innocent character of the corrole ligand.

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Bibliographic Details
Main Authors: Stefanelli, Manuela, Nardis, Sara, Tortora, Luca, Fronczek, Frank R., Smith, Kevin M., Licoccia, Silvia, Paolesse, Roberto
Format: Artigo
Language:Inglês
Published: 2011
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3070942/
https://ncbi.nlm.nih.gov/pubmed/21380423
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c0cc05491g
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